(N-Heterocyclic-Carbene)Copper(I)-Catalyzed Carbon-Carbon Bond Formation Using Carbon Dioxide

نویسندگان

  • Gergely Sirokman
  • Richard R. Schrock
چکیده

Alkynes and olefins insert into [(IPr)CuH] 2 (IPr = N,N-bis-(2,6diisopropylphenyl)-1,3-imidazol-2-ylidene) to give copper vinyl and copper alkyl complexes. These copper complexes insert CO2 into the Cu-C bond to form copper acrylate and copper carboxylate complexes. Acrylic and carboxylic acids can be isolated

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تاریخ انتشار 2007